POTASSIUM CHLORIDE

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Basic information

  • Chemical formula(s): \({\rm KCl}\)
  • Other names: Muriate of potash, potassium muriate, sylvite
  • CAS number: 7447-40-7
  • EC number: 231-211-8
  • Molecular weight: 74.55 g/mol
  • International Chemical Safety Card (ICSC): 1450
  • Flammability: no
  • Description: White crystalline solid salt. Highly soluble in water. Not classified as hazardous under GHS regulations.

NFPA 704 (fire diamond)

  • Health (blue): 1 - poses no health hazard, requires no precautions, and would offer no hazard beyond that of ordinary combustible materials.
  • Flammability (red): 0 - will not burn under typical fire conditions.
  • Instability–reactivity (yellow): 0 - normally stable, even under fire exposure conditions, and is not reactive with water.
  • Special notice (white): -

Hazard statements

Potassium chloride is not classified as a hazardous substance according to GHS (Globally Harmonized System). Therefore, no H-codes are assigned.

Code Phrase
- No hazard statements assigned

Precautionary statements

Despite not being classified as hazardous, the following precautionary measures are recommended for safe handling:

Code Phrase
P261 avoid breathing dust/fume/gas/mist/vapours/spray
P264 wash hands thoroughly after handling
P280 wear protective gloves/protective clothing/eye protection/face protection
P302+P352 IF ON SKIN: wash with plenty of water
P304+P340 IF INHALED: remove person to fresh air and keep comfortable for breathing
P305+P351+P338 IF IN EYES: rinse cautiously with water for several minutes, remove contact lenses if present and easy to do, continue rinsing

Protective measures

Gloves

For routine handling of potassium chloride powder or solutions:

  • Nitrile: good - suitable for routine handling and protection from dust.
  • Natural latex or rubber: good - adequate for normal contact.
  • PVC: fair - suitable for basic protection.
  • Leather work gloves: poor - not recommended for chemical handling.

Safety goggles

  • Wear safety glasses with side shields when handling powder to prevent eye irritation from dust.
  • Corrective glasses are not considered safety goggles.
  • Standard safety glasses adequate for routine use.

Clothing

  • Wear long sleeves and long pants to minimize skin contact with dust.
  • Standard laboratory clothing is sufficient.
  • Remove contaminated clothing and wash before reuse.
  • Closed-toe shoes required.

Respiratory protection

  • Ensure adequate ventilation when handling large quantities.
  • Use dust mask if working with fine powder in poorly ventilated areas.
  • N95 respirator recommended for handling large quantities of fine powder.

Spill management

  • Use standard cleanup procedures for non-hazardous materials.
  • Sweep up or vacuum material and place in appropriate waste container.
  • Avoid creating dust clouds during cleanup.
  • Use water to dampen material if dusty conditions exist.
  • Clean area with water after material removal.
  • Dispose according to local waste management regulations.
  • No special disposal requirements - can typically be disposed as non-hazardous waste.

Special warnings

  • Generally recognized as safe (GRAS) - potassium chloride is used as a food additive and salt substitute.
  • Low toxicity - oral LD50 in rats: 2600 mg/kg, indicating low acute toxicity.
  • May cause mild irritation - dust may cause minor irritation to eyes, skin, or respiratory tract.
  • Hygroscopic - absorbs moisture from air, store in tightly closed containers.
  • Store in cool, dry place away from moisture.
  • Compatible with most materials - no significant incompatibilities under normal conditions.
  • Large ingestion may cause gastrointestinal irritation - though this is unlikely in laboratory quantities.